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The feature that enables the automatic assignment of cases to agents is Case Assignment Rules. These rules allow organizations to define criteria for how cases should be directed to specific users or queues based on parameters such as case origin, priority, type, or other custom fields. This ensures that cases are promptly routed to the most appropriate resources, enhancing response times and customer service efficiency.

In contrast, the other options provide different functionalities. Web to Case and Email to Case are methods for creating cases from web forms and emails, respectively, but they do not inherently manage the routing of those cases to agents. Case Escalation Rules pertain to increasing the visibility and urgency of cases based on conditions, such as time elapsed without resolution, rather than assigning the initial ownership of cases. Therefore, Case Assignment Rules is the definitive feature for automating case assignments to agents, streamlining the case management process.